Bis[4-(4-pyridyl)pyridinium] μ-4,4′-bipyridine-bis[tetraaqua(4,4′-bipyridine)manganese(II)] bis(5-sulfonatobenzene-1,3-dicarboxylate) 4,4′-bipyridine solvate pentadecahydrate
نویسندگان
چکیده
منابع مشابه
Bis[4-(4-pyridyl)pyridinium] μ-4,4′-bipyridine-bis[tetraaqua(4,4′-bipyridine)manganese(II)] bis(5-sulfonatobenzene-1,3-dicarboxylate) 4,4′-bipyridine solvate pentadecahydrate
The crystal structure of the title compound, (C(10)H(9)N(2))(2)[Mn(2)(C(10)H(8)N(2))(3)(H(2)O)(8)](C(8)H(3)O(7)S)(2)·C(10)H(8)N(2)·15H(2)O, consists of dinuclear Mn(II) complex cations, sulfonato-benzene-dicarboxyl-ate trianions, 4-(4-pyridyl)pyridinium cations, uncoordin-ated 4,4'-bipyridine and uncoordinated water mol-ecules. One 4,4'-bipyridine mol-ecule bridges two Mn atoms, forming a centr...
متن کاملμ-Oxalato-bis[bis(2,2′-bipyridine)manganese(II)] bis(perchlorate) 2,2′-bipyridine solvate
The unit cell of the title compound, [Mn(2)(C(2)O(4))(C(10)H(8)N(2))(4)](ClO(4))(2)·C(10)H(8)N(2), consists of a binuclear cation, two perchlor-ate anions, and one solvent 2,2'-bipyridine (bpy) mol-ecule. In the complex cation [Mn(2)(C(2)O(4))(C(10)N(2)H(8))(4)](2+), two Mn(II) atoms are bridged by a bis-(bidentate) oxalate ligand, each Mn(II) atom being further coordinated by two bpy ligands i...
متن کاملcatena-Poly[[diaquabis(thiocyanato-κN)cobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] 4,4′-bipyridine solvate]
In the title complex, {[Co(NCS)(2)(C(10)H(8)N(2))(H(2)O)(2)]·C(10)H(8)N(2)}(n), the Co(II) ion is located on an inversion centre and is coordinated by two N atoms from the two 4,4'-bipyridine ligands, two O atoms from the water mol-ecule, and two N atoms from two isothio-cyanate ions in a distorted octa-hedral environment. In the crystal, the coordinated water mol-ecules, isothio-cyanate ions a...
متن کاملcatena-Poly[[[bis(μ-4-hydroxybenzoato)bis[(4-hydroxybenzoato)manganese(II)]]-di-μ-4,4′-bipyridine] 4,4′-bipyridine disolvate tetrahydrate]
In the polymeric title complex, {[Mn(O(2)CC(6)H(4)-p-OH)(2)(C(10)H(8)N(2))]·C(10)H(8)N(2)·2H(2)O}(n), the Mn(II) atom is coordinated in a distorted octa-hedral geometry defined by four O atoms from three different carboxyl-ate ligands and two trans-N atoms from two 4,4'-bipyridine ligands. In the crystal structure, an extensive range of O-H⋯O and O-H⋯N hydrogen bonds link the complex and all no...
متن کاملPoly[[[tetraaquacobalt(II)]-μ-bipyridine] terephthalate]
The Co(II) atom in the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(8)H(4)O(4))}(n), is coordinated by two N atoms of two bipyridine ligands and four O atoms of four water mol-ecules in an octahedral geometry. The one-dimensional [Co(C(10)H(8)N(2))(H(2)O)(4)](2+) cation chain is further extended into a supra-molecular network via O-H⋯O hydrogen-bond inter-actions. The Co atom lies on a twofo...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809028359